Fast Charge and High Stability of Solid?State Graphite Organic Ionic Plastic Crystal Composite Anodes

All-solid-state batteries (ASSBs) using organic ionic plastic crystals (OIPCs) are promising candidates to overcome the inherent safety issues of lithium-ion (LIBs). Although OIPCs have excellent process applicability in roll-to-roll electrode fabrication process, their application as solid electrolytes incorporated composite electrodes has yet be demonstrated detail. Herein, we denote positive effect N-ethyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide ([C2mpyr][FSI]) within a graphite anode on charge rate capability and cycle life. The highest capacity ratio (the at 2C vs. that measured 0.1C) was for with an OIPC 50 wt % (89.5 %, 295.7 mAh/g charge), almost same liquid electrolyte (85.7 295.9 charge). More favorable conduction pathways were resolved higher ratio, whereas excessive amount reduced long-term cyclability. most stable discharge retention obtained 30 (257.4 100th discharge), which showed no signs fading 100 cycles. lithiation/delithiation solid-state graphite-[C2mpyr][FSI] evaluated reversible. In addition, enhanced electrolyte/electrode electrode/current collector contacts. This work highlights multiple advantageous functions anode, will broaden our horizons use composites ASSBs.